Chemistry 2008 Jamb Examination

Chemistry 2008 Jamb Examination
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Question 1

Chlorophyll obtained from green leaves of plant can be shown to be composed of more than one coloured component by the technique of
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The chlorophyll from the green leaves of plant being a mixture can be separated by Chromatography into its different components. Chromatography has to do with the separation of coloured components. chromatography is used in industrial processes to purify materials, test trace amounts of contaminants, isolate chiral compounds, and quality control test products
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Question 2

In countries where the temperature falls below 273K, salt is always sprinkled on the icy road in order to
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The presence of impurities in a substance lowers the melting point. Salt is added on icy roads to cause the ice to melt on time.
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Question 3

2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)  
From the equation above, calculate the mass of sodium hydroxide produced by 2.3g of sodium. [H = 1, O = 16, Na = 23]
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2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g)
Relative molecular mass of NaOH = 23 + 16 + 1 = 40gmol-1
2 * 23g of sodium react with water to produce
2 * 40g of NaOH
∴ 2.3g of sodium will react with water to produce
(2.3 * 40 * 2)/(23 * 2) = 4.00g
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Question 4

16.8g of sodium hydrogen trioxocarbonate (IV) is completely decomposed by heat. Calculate the volume of carbon(IV) oxide given off at s.t.p.}
[Na = 23, C = 12, O = 16, H = 1, Molar volume of a gas at s.t.p } = 22.4$dm^3$
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The decomposition reaction:
NaHCO3 → Na2CO3 + CO2 + H2O
Molar mass of NaHCO3:
M = 23 + 1 + 12 + (3 $\times$ 16) = 84g/mol
Number of moles of $NaHCO_3$:
n = $\dfrac{16.8}{84} = 0.2 mol$

From the equation, 2 moles of $NaHCO_3$ produce 1 mole of $CO_2$, so 0.2 mol $NaHCO_3$ produces:
$n_{CO_2}$ = 0.2 $\times \dfrac{1}{2} = 0.1 mol$

Volume of $CO_2$ at s.t.p: V =
$n_{CO_2} \times 22.4 = 0.1 \times 22.4 = 2.24 dm^3$

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Question 5

300cm$^3$ of gas has a pressure of 800mmHg. If the pressure is reduced to 650mmHg, find its volume.
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Using Boyle's Law: P1V1 = P2V2
P1 = 800 mmHg, V1 = 300 cm3, P2 = 650 mmHg$$V_2 = \dfrac{P_1 V_1}{P_2} $$$$= \dfrac{800 \times 300}{650} \approx 369.23\,\text{cm}^3$$$$\therefore \text{The new volume is } 369.23\,\text{cm}^3$$
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Question 6

Diffusion is slowest in solid particles than in particles of liquid and gases because
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In solids, particles are closely packed in fixed positions with very strong intermolecular forces. This restricts their movement, giving them very low kinetic energy compared to particles in liquids and gases. Since diffusion is driven by particle motion, solids diffuse the slowest because their particles vibrate about fixed points and cannot move freely.
Therefore Diffusion is slowest in solids because they have less kinetic energy.
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Question 7

The experiment that showed that atoms have tiny positively charged nucleus was first carried out by
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Rutherford’s gold foil experiment involved bombarding thin gold foil with alpha particles. Most passed through, but a few were deflected, indicating a small, dense, positively charged center in the atom (the nucleus). This overturned Thomson’s plum pudding model and led to the nuclear model of the atom.
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Question 8

The atom of an element X is represented as yzX. The basic chemical properties of X depends on the value of
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An atom is represented as: \[ ^{Y}_{Z}X \] Here, \(Y\) is the mass number (protons + neutrons), \(Z\) is the atomic number (protons/electrons). The chemical properties of an element are determined by the number of electrons, which equals the atomic number, \(Z\). \[ \therefore \; \text{Chemical properties depend on } Z. \]
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Question 9

Electronic Configuration of Oxygen
The diagram above represent the electron sub-level for
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The diagram shows the electron sub-levels. For Oxygen (atomic number 8), the configuration is: \[ 1s^2 \, 2s^2 \, 2p^4 \] 
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Question 10

In the periodic table, the electrical and thermal conductivities are properties of elements that
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Metals conduct heat and electricity due to delocalized electrons. Across a period, metallic character decreases (left to right), so conductivity decreases. Down a group of metals, atomic size increases but metallic character strengthens, so conductivity increases. 
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Chemistry 2008 Jamb Examination
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