Chemistry 2007 Jamb Examination

Chemistry 2007 Jamb Examination
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Question 1

Trioxonitrate (V) acid is not used for preparing hydrogen gas from metals because it:
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Hydrogen is usually prepared with dilute HCl or H₂SO₄.

HNO₃ is not used because it is a strong oxidizing agent, converting the liberated hydrogen into water:

\[ 2HNO₃ + Zn → Zn(NO₃)₂ + H₂ \]

Then: \[ 2H₂ + O₂ → 2H₂O \]

Thus, hydrogen is not collected. Correct option A.

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Question 2

An element used in the production of matches is:
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The striking surface of matches contains red phosphorus, while the matchstick head contains antimony (III) sulfide and sulphur.

Thus, sulphur is directly involved in match production. Correct option D.

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Question 3

When calcium oxide is heated with carbon, the oxide will:
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On heating, CaO reacts with carbon to form calcium carbide:

\[ CaO + 3C → CaC₂ + CO \]

Thus, the product is carbide. Correct option A.

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Question 4

A solution which on treatment with hydrochloric acid produces a colourless, odourless gas which turns lime water milky is most likely to be:
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The reaction is:

CaCO3 + 2HCl → CaCl2 + H2O + CO2

The gas (CO2) is colourless, odourless and turns limewater milky:

Ca(OH)2 + CO2 → CaCO3 ↓ + H2O

So the correct answer is trioxocarbonate (IV). Option C.

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Question 5

The soft solder used for welding and plumbing is an alloy of:
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Soft solder is an alloy of lead (Pb) and tin (Sn), usually in about 50:50 ratio.

It has a low melting point and is used in plumbing and electronics.

Correct option A.

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Question 6

The reddish-brown rust on iron roofing sheets consists of:
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Rust is hydrated iron (III) oxide, generally written as Fe₂O₃·3H₂O.

It forms when iron reacts with oxygen and water. Correct option C.

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Question 7

Na₂S₂O₃(aq) + 2HCl(aq) → 2NaCl(aq) + H₂O(l) + SO₂(g) + S(s). Which of the following would introduce the greatest increase in the rate of the chemical reaction above?
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Reaction rate generally increases with higher temperature (more energetic collisions) and higher concentration (more frequent collisions).

Thus, the greatest increase is from both together. Correct option D.

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Question 8

The tincture of iodine means iodine dissolved in:
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Tincture of iodine is a solution of iodine in ethanol with some water, used as an antiseptic.

Correct option A.

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Question 9

Cu²⁺(aq) + 4NH₃(g) ↔ [Cu(NH₃)₄]²⁺(aq). In the reaction above, what is the effect of precipitating Cu²⁺(aq) as CuS(s)?
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If Cu²⁺ is removed (by precipitation as CuS), the equilibrium shifts left (Le Chatelier’s principle). This releases NH₃ back into solution, increasing free NH₃.

So, more NH₃(g) remains. Correct option B.

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Question 10

Copper and silver metals are commonly used as coin because they are:
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Copper and silver resist corrosion because they are not easily oxidized. This makes them durable for coinage.

Correct option D.

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Chemistry 2007 Jamb Examination
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