Chemistry 2017 Jamb Examination

Chemistry 2017 Jamb Examination
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Question 21

\[^{226} _{88}Ra → ^x _{86} Rn + \text{alpha particle}\]
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In an alpha decay, the nucleus emits an alpha particle \( ^4_2\text{He} \), which reduces the mass number by 4 and the atomic number by 2.
Given:\[ ^{226}_{88}\text{Ra} \rightarrow ^{x}_{86}\text{Rn} + ^{4}_{2}\text{He} \]Applying the law of conservation of mass number:\[ 226 = x + 4 \Rightarrow x = 226 - 4 = 222 \]Thus, the resulting element is radon-222.
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Question 22

The shape of ammonia molecules is
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Ammonia (NH3) has three bonding pairs and one lone pair of electrons on the nitrogen atom.
According to VSEPR theory, the electron pairs repel each other, resulting in a trigonal pyramidal geometry with bond angle approximately 107°.
The lone pair compresses the bond angles slightly from the tetrahedral angle (109.5°).
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Question 23

The mass of silver deposited when a current of 10A is passed through a solution of silver salt for 4830s is – (Ag = 108, F = 96500 C mol−1)
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Using Faraday’s first law of electrolysis:\[ m = \dfrac{EIt}{F} \]where \(E = 108\), \(I = 10\,A\), \(t = 4830\,s\), and \(F = 96500\).\[ m = \dfrac{108 \times 10 \times 4830}{96500} \]\[ m = 54.0\,g \]Hence, 54 g of silver will be deposited.
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Question 24

Tin is unaffected by air at ordinary temperature due to its?
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Tin forms a thin, protective layer of oxide (SnO2) when exposed to air at room temperature.
This oxide coating prevents further oxidation, showing that tin has a weak electropositive character compared to other metals.
Thus, it resists corrosion in ordinary air conditions.
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Question 25

Calculate the amount in moles of silver deposited when 9650C of electricity is passed through a solution of silver salt (F = 96500 C mol−1).
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From Faraday’s law:\[ n = \dfrac{Q}{F} \]where \( Q = 9650 \; C \) and \( F = 96500 \; C \; mol^{-1} \).\[ n = \dfrac{9650}{96500} = 0.10 \; mol \]Hence, 0.10 mole of silver is deposited.
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Question 26

The reaction of halogens with alkanes in the presence of sunlight is an example of
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Halogens react with alkanes under ultraviolet light through a free radical mechanism.
In this process, a hydrogen atom in the alkane is replaced by a halogen atom, forming haloalkanes.
This is a typical substitution reaction known as halogenation of alkanes.
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Question 27

The enzyme used in the hydrolysis of starch to dextrin and maltose is?
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Amylase catalyses the breakdown of starch (a polysaccharide) into simpler sugars such as dextrin and maltose.
It acts on the α-1,4-glycosidic bonds present in starch.
Lipase acts on fats, invertase acts on sucrose, and zymase functions in fermentation.
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Question 28

The alkyl group is represented by the general formula
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Alkyl groups are derived from alkanes by the removal of one hydrogen atom.
The general formula for alkanes is CnH2n+2.
Removing one hydrogen gives CnH2n+1.
Hence, the alkyl group formula is CnH2n+1.
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Question 29

Cu2S(g) + O2(g) → 2Cu + SO2(g)
What is the change in the oxidation number of copper in the reaction?
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In Cu2S, each copper atom has an oxidation number of +1 because sulphur has −2.

Cu2S
2 Cu - 2(1) = 0
2 Cu = 2$$Cu = \dfrac{2}{2} = +1$$ In the products, copper exists as the free metal with an oxidation number of 0.
Therefore, copper is reduced from +1 to 0, indicating a reduction process.
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Question 30

In the diagram above. X is  A. SO3 B. SO2 C. S D. H2S
In the diagram above, X is
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The setup represents the production of sulfur dioxide. And the cylinder marked X is SO2

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Chemistry 2017 Jamb Examination
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