Chemistry 2018 Jamb Examination

Chemistry 2018 Jamb Examination
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Question 41

When air which contains the gases oxygen, nitrogen, carbon dioxide, water vapour and the rare gases is passed through alkaline pyrogallol and then over quicklime, the only gases left are:
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Alkaline pyrogallol absorbs oxygen gas, while quicklime (CaO) removes carbon dioxide by forming calcium carbonate. The remaining gases—nitrogen and the rare (noble) gases—do not react with either reagent and therefore remain in the mixture.
Hence, after the absorption process, only nitrogen and the rare gases are left.
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Question 42

In the laboratory preparation of oxygen, the gas cannot be collected by downward displacement of air because
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Oxygen has almost the same density as air, making separation by displacement inefficient. Since the two gases mix readily, collecting oxygen by downward displacement of air is impractical. Therefore, it is collected over water or by upward delivery instead.
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Question 43

2KClO₃(s) → 2KCl(s) + 3O₂(g)
The importance of the catalyst in the reaction above is that
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Potassium chlorate decomposes to give oxygen gas when heated, and manganese(IV) oxide is commonly used as a catalyst. The catalyst lowers the activation energy and allows the reaction to proceed faster at a lower temperature without affecting the amount of oxygen produced.
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Question 44

Which of the following is used to power steam engines?
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Steam engines are traditionally powered by the combustion of coal. The heat generated from burning coal is used to convert water into steam, which drives the engine pistons or turbines to produce mechanical work.
Hence, coal is the fuel used to power steam engines.
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Question 45

In the reaction between sodium hydroxide and sulphuric acid solutions, what volume of 0.5 molar sodium hydroxide would exactly neutralise 10 cm³ of 1.25 molar sulphuric acid?
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The reaction is 2NaOH + H2SO4 → Na2SO4 + 2H2O .
\( C_1V_1/n_1 = C_2V_2/n_2 \)
For NaOH: \( C_1 = 0.5, n_1 = 2 \)
For H₂SO₄: \( C_2 = 1.25, V_2 = 10, n_2 = 1 \)\[ V_1 = \dfrac{C_2V_2n_1}{C_1n_2}\]\[ = \dfrac{1.25 \times 10 \times 2}{0.5 \times 1} = 50 \; \text{cm}^3 \]Thus, 50 cm³ of 0.5 M NaOH will exactly neutralise 10 cm³ of 1.25 M H₂SO₄.
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Question 46

To what volume must 300 cm³ of 0.60 M sodium hydroxide solution be diluted to give a 0.40 M solution?
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Using the dilution formula \( C_1V_1 = C_2V_2 \):
\( 0.60 \times 300 = 0.40 \times V_2 \)
\( V_2 = \dfrac{0.60 \times 300}{0.40} = 450 \; \text{cm}^3 \)
Therefore, the solution must be diluted to 450 cm³ to achieve a 0.40 M concentration.
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Question 47

Diamond is a bad conductor of electricity because its bonding electrons are used in
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Each carbon atom in diamond forms four strong covalent bonds in a tetrahedral arrangement, using all its valence electrons. This leaves no free electrons or mobile charge carriers for conduction, making diamond an electrical insulator.
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Question 48

The reaction between an organic acid and an alcohol in the presence of an acid catalyst is known as:
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An organic acid reacts with an alcohol in the presence of an acid catalyst (usually concentrated Hâ‚‚SOâ‚„) to form an ester and water. This process is known as esterification.
Example: \( CH_3COOH + C_2H_5OH \xrightarrow{H_2SO_4} CH_3COOC_2H_5 + H_2O \)
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Question 49

The constituent common to duralumin and alnico is
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Both duralumin and alnico contain aluminium (Al).
Duralumin is an alloy of aluminium, copper, magnesium, and manganese, while alnico is made of aluminium, nickel, and cobalt. Therefore, aluminium is the common constituent between the two alloys.
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Question 50

The solubility of solids that dissolve in a given solvent with the liberation of heat will
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When dissolution is exothermic (heat is released), increasing the temperature shifts the equilibrium to favour the undissolved solid, reducing solubility.
Therefore, solubility decreases with an increase in temperature for such substances.
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Chemistry 2018 Jamb Examination
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